Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8002762 | Journal of Alloys and Compounds | 2013 | 5 Pages |
Abstract
This study reports a novel strategy of preparing CoS2/reduced graphene oxides (RGO) nanocomposites by employing graphene oxides (GO) as an oxidizing agent and Na2S2O3 as a reducing agent. CoS2 can be in situ synthesized with GO being reduced. X-ray diffraction (XRD), Raman spectrometry, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electrochemical test are used to characterize the nanocomposite. The CoS2 particles with the size of 150Â nm are dispersed in the networks made from thin RGO nanosheets. The CoS2/RGO nanocomposite as an anode material for lithium-ion batteries can deliver excellent reversible capacity retention (640Â mAÂ hgâ1) after cycling 50 times when tested at 100Â mAÂ gâ1 and rate performance. The enhanced electrochemical properties can be attributed to the nanoscale particles sizes of CoS2 in addition to the effects of RGO networks in preventing the agglomeration of CoS2 and absorbing lithium polysulfides during the charge-discharge processes.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Bin Qiu, Xiuyun Zhao, Dingguo Xia,