Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8013862 | Materials Letters | 2018 | 14 Pages |
Abstract
Plasma electrolytic oxidation of zirconium in alkaline solution containing Er2O3 powder was used for preparation of ZrO2:Er3+ coatings. Photoluminescence (PL) emission spectra of ZrO2:Er3+ excited by ultraviolet irradiation are composed of broad PL band associated with ZrO2 host and sharp bands corresponding to f-f transitions of Er3+. The strongest green PL emission band of Er3+ in the range from 540â¯nm to 580â¯nm is assigned to 4S3/2â¯ââ¯4I15/2 transition. The PL excitation spectra of ZrO2:Er3+ characterize broad band from 250â¯nm to 350â¯nm associated with charge transfer state of Er3+ and the series of peaks in the range from 350â¯nm to 530â¯nm which are associated with 4f transitions of the Er3+ from ground state 4I15/2 to higher levels. Obtained results allowed the identification of down-conversion PL mechanism.
Related Topics
Physical Sciences and Engineering
Materials Science
Nanotechnology
Authors
Stevan StojadinoviÄ, Nenad TadiÄ, Rastko VasiliÄ,