| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 8015179 | Materials Letters | 2018 | 10 Pages |
Abstract
Highly dispersed Rh particles supported on Ce0.75Zr0.25O2-δ mixed with alumina were prepared by sorption-hydrolytic deposition technique. Produced catalyst exhibited high activity in autothermal reforming of n-hexadecane, but suffered from coking. Structured Rh/Ce0.75Zr0.25O2-δ-Æ-Al2O3/FeCrAl catalyst was prepared by strongly bound catalytic coating deposition onto metallic wire mesh to provide effective heat transfer and avoid coking. Rh/Ce0.75Zr0.25O2-δ-Æ-Al2O3/FeCrAl showed excellent performance in n-hexadecane autothermal reforming providing 100% conversion and stable operation for at least 12â¯h on stream without detection of any carbon deposits.
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Authors
T.B. Shoynkhorova, V.N. Rogozhnikov, P.A. Simonov, P.V. Snytnikov, A.N. Salanov, A.V. Kulikov, E.Y. Gerasimov, V.D. Belyaev, D.I. Potemkin, V.A. Sobyanin,