Article ID Journal Published Year Pages File Type
8023701 Surface and Coatings Technology 2018 11 Pages PDF
Abstract
The degradation of micro-arc oxidation coating (MAO)/chitosan (CS) coating decreases solution pH value at lower level (≤8.25) in comparison to MAO coating. A self-degradation mechanism of CS-based materials is proposed. And the degradation process experiences three stages: (1) initial water diffusion, absorption and hydration of CS coatings; (2) gradual decrease in molecular weight; and (3) scission and dissolution of oligomers and monomers. Thus, the degraded CS releases -NH3+ ions, which react with MgO of MAO coating and lead to the formation of Mg2+ ions and water along with the micro-cracks and pores of the MAO coating.272
Related Topics
Physical Sciences and Engineering Materials Science Nanotechnology
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