Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8023767 | Surface and Coatings Technology | 2018 | 23 Pages |
Abstract
Ti-Al-N is widely used as protective coating in various industrial applications. Here, we investigate the influence of Ta content - ranging from 0 to 28â¯at.% on the metal sublattice - on the mechanical properties, thermal stability, and high temperature oxidation resistance of arc evaporated Ti-Al-N coatings. We found an increase in hardness from 30.0â¯Â±â¯1.0â¯GPa for Ti0.54Al0.46N to 35â¯Â±â¯0.7â¯GPa for Ti0.44Al0.41Ta0.15N. Furthermore, age hardening due to spinodal decomposition of the supersaturated solid solution into cubic AlN-, TiN-, and TaN-rich domains lead to maximum hardness values of 39.5â¯Â±â¯1.0â¯GPa upon annealing to 1100â¯Â°C for Ti0.38Al0.34Ta0.28N. This behaviour is directly linked with the extremely retarded formation of wurtzite structured (w) AlN. Even after annealing Ti0.38Al0.34Ta0.28N at the maximum temperature of 1100â¯Â°C, no crystalline w-AlN phase could be detected. Additionally, the incorporation of Ta to Ti-Al-N leads to a significantly higher oxidation resistance. While Ti0.54Al0.46N is already fully oxidised during exposure to ambient air at 900â¯Â°C, following a linear like oxide scale growth kinetic with 2.96â¯Â±â¯0.48â¯Î¼m/h, the Ti0.49Al0.44Ta0.07N and Ti0.44Al0.41Ta0.15N coatings provide the lowest parabolic-like oxide growth rates of 7.1â¯Â±â¯0.4·10â2â¯Î¼m2/h. The even higher-Ta-containing Ti0.38Al0.34Ta0.28N exhibits already a much higher oxide scale growth rate of 23.1â¯Â±â¯1.7·10â2â¯Î¼m2/h. Consequently, the Ta content for an optimised oxidation resistance needs to be balanced to the Ti content of the Ti-Al-N coatings.
Related Topics
Physical Sciences and Engineering
Materials Science
Nanotechnology
Authors
W.M. Seidl, M. Bartosik, S. Kolozsvári, H. Bolvardi, P.H. Mayrhofer,