Article ID Journal Published Year Pages File Type
8030406 Surface and Coatings Technology 2013 11 Pages PDF
Abstract
► Grain refinement is due to change in nucleation, growth and defect structure. ► Nucleation mode is changed from instantaneous to progressive with thiourea addition. ► Growth is inhibited by segregation of thiourea at the grain boundaries. ► The copper electrodeposit prepared without addition of thiourea reveals dislocations. ► Grain refinement is due to predominant formation of twins in presence of thiourea.
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Physical Sciences and Engineering Materials Science Nanotechnology
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