Epitaxial growth of indium oxyfluoride thin films by reactive pulsed laser deposition: Structural change induced by fluorine insertion into vacancy sites in bixbyite structure

InOxFy thin films were epitaxially grown on Y-stabilized ZrO2 (111) substrates by reactive pulsed laser deposition. By changing the substrate temperature (TS), we were able to control the fluorine content of the film. Phase-pure epitaxial thin films with bixbyite-like ordering in the anion-site occupancy were obtained at high TS (≥ 240 °C), where fluorine was inserted into the vacancy sites in the bixbyite lattice up to y / (x + y) ~ 0.3. By decreasing TS, y / (x + y) increased and the bixbyite-like ordering disappeared; simultaneously, fluorine-rich and fluorine-poor subphases emerged. The films grown at TS ≤ 150 °C were amorphous and exhibited higher optical absorbance and electrical resistivity than the epitaxial films.