Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8046997 | Applied Clay Science | 2014 | 4 Pages |
Abstract
In this study, the exfoliated montmorillonite was prepared through the click chemistry of a propargyl-containing intercalator with singly or multiply azido-functionalized polyhedral oligomeric silsesquioxane nanoparticles. Thermogravimetric analyses revealed that the pyrolysis kinetics had a close relationship to the layered structures, exfoliated structures, and cage-like molecules of polyhedral oligomeric silsesquioxane nanoparticles. The pyrolysis of exfoliated montmorillonite had a mechanism function of Avrami-Erofeev equation, and the kinetic compensation effect equation revealed the pyrolysis.
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Authors
Hui-Wang Cui, Shiao-Wei Kuo,