Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8047016 | Applied Clay Science | 2014 | 5 Pages |
Abstract
The results show that the adsorption of 4-chloroaniline was greatly enhanced by using a sulfuric acid-treated halloysite, as compared to the unmodified halloysite. A comparison of kinetic models applied to the adsorption of chloroanilines on an acid-treated halloysite was evaluated for pseudo first-order, pseudo second-order, and intraparticle diffusion kinetic models. The chemisorption pseudo-second order kinetic model was found to correlate the experimental data well. The adsorption mechanism of acid-treated halloysite -chloroaniline system complied well with the Langmuir model in the case of 4-chloroaniline and 3,4-dichloroaniline and with the Freundlich model for 3-chloroaniline.
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Authors
Beata Szczepanik, Piotr SÅomkiewicz, Magdalena Garnuszek, Kamil Czech,