Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8070782 | Energy | 2018 | 16 Pages |
Abstract
Development of convenient, economic and large scale catalysts for oxygen reduction reaction (ORR) in alkaline medium is of great significance to practical applications of aluminum-air batteries. Herein, a corn-stover-derived, nitrogen and cobalt co-doped porous biocarbon material has been prepared and utilized as ORR catalysts in aluminum-air batteries. The resultant product (NCAC-Co) exhibits an interconnected hierarchical porous structure with a high specific surface area (1877.3â¯m2â¯gâ1). The electrocatalytic characterization of NCAC-Co reveals a half-wave potential (0.743â¯V vs. RHE) only slightly lower than that of commercial Pt/C (0.793â¯V vs. RHE) in alkaline medium. Moreover, NCAC-Co also demonstrates the mechanism of 4-electron oxygen reduction (nâ¯=â¯3.87) and outstanding durability. The excellent ORR performance of NCAC-Co can be attributed to the presence of pyridinic N, graphitic N and Co nanoparticles as well as the interconnected hierarchical porous structure. More importantly, NCAC-Co also delivers a good behavior when applied in aluminum-air batteries. The work presented herein shows the NCAC-Co derived from corn stover holds good promise to be an alternative of economic and large scale catalysts for metal-air batteries.
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Authors
Zhenning Liu, Zhiyuan Li, Jian Ma, Xu Dong, Wen Ku, Mi Wang, Hang Sun, Song Liang, Guolong Lu,