Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8101536 | Journal of Cleaner Production | 2016 | 10 Pages |
Abstract
Atomic Layer Deposition (ALD) technology has been under rapid development toward a broad array of applications, while the low deposition efficiency and heavy waste of TMA are limiting its industrial-scale applications. In this paper, a mathematical model is developed based on an experimental ALD of alumina process, and an optimization approach is then proposed to investigate the optimal ALD operating for the minimum TMA wastes and the maximum Al2O3 production under various conditions. Results show that the maximum TMA adsorption and alumina production cannot be achieved simultaneously, but sufficient H2O dosing can minimize the gap between them. The influence of substrate surface saturation condition and operating temperature is also investigated. Results quantitatively show that lower surface saturation condition requires more ALD cycles to improve the precursors' utilization efficiency, while the optimal ALD process can increase the maximum alumina production from2.7 Ã 10â4 mol/m2 to 7.5 Ã 10â4 mol/m2 with the temperature rise from 150 °C to 200 °C. Besides, it is found that the maximum production of both |-Al(CH3)2 and alumina is influenced by their corresponding half-cycle duration, and sufficient treatment time can significantly improve the ALD process efficiency and reduce the total TMA waste. These insights into the minimum TMA waste and maximum production of surface products can guide the future design of ALD of alumina process with better efficiency and sustainability.
Related Topics
Physical Sciences and Engineering
Energy
Renewable Energy, Sustainability and the Environment
Authors
Yuanyuan Xie, Dongqing Pan, Lulu Ma, Chris Yuan,