Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8152823 | Journal of Magnetism and Magnetic Materials | 2018 | 16 Pages |
Abstract
Bulk cobalt ferrite, being a hard ferrite, shows high magnetization, high resistivity and high coercivity. If thin films of cobalt ferrite can be deposited at a low enough temperature and if its coercivity can be reduced, cobalt ferrite will make a very good candidate for use as a magnetic core of an integrated inductor in RF-CMOS ICs. Though polycrystalline and epitaxial thin films of cobalt ferrite have been made by various techniques, there are no reports of thin films of superparamagnetic cobalt ferrite. In this work, nanocrystalline cobalt ferrite thin films, which are superparamagnetic as deposited, have been prepared in the solution medium at â¼190â¯Â°C, using microwave irradiation. The as-prepared films have a saturation magnetization (MS) of 401 emu/cc and coercivity (HC) of 19 Oe at room temperature for a crystallite size of 2â¯nm. The cobalt ferrite powder obtained as a by-product during the same process has MS of 50â¯emu/g and HC of 5 Oe at room temperature, making it superparamagnetic. The as-prepared films were annealed in air at 300â¯Â°C for 5â¯min and 10â¯min. Annealing for 10â¯min results in an increase in crystallite size to 36â¯nm, MS increases from 401 emu/cc to 545 emu/cc, and HC increases from 19 Oe to 860 Oe. The change in magnetic properties can be directly associated with change in the crystallite size and degree of crystallographic inversion, as determined by neutron diffraction and deduced from X-ray photoelectron spectroscopy.
Related Topics
Physical Sciences and Engineering
Physics and Astronomy
Condensed Matter Physics
Authors
Neelima Sangeneni, KM Taddei, Navakanta Bhat, SA Shivashankar,