Article ID Journal Published Year Pages File Type
869437 Biosensors and Bioelectronics 2007 6 Pages PDF
Abstract

DNA template driven CdSe nanobeads (NBs) and nanowires (NWs) have been synthesized by an electrodeposition technique. The synthesis protocol has yielded randomly oriented cubic CdSe NBs with mean size ∼3.0 nm in presence of single stranded DNA, poly G(30). Monocrystalline cubic CdSe NWs of width ∼4.0 nm with string-like morphology have been achieved when synthesized in presence of both poly G(30) and its conjugate, poly C(30). Optical absorption of CdSe NBs show a blue shift of 0.8 eV and long wavelength tailing where as NWs show steep increase of absorption in shorter wavelength regime accompanied by a further blue shift. DNA tags to the NBs or NWs have been confirmed from Fourier transform infrared spectroscopy measurements. Biomolecular recognition with CdSe NWs have been established by photoluminescence measurements.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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