Article ID Journal Published Year Pages File Type
8850189 Chemie der Erde - Geochemistry 2018 24 Pages PDF
Abstract
Fractional crystallization of Sugarloaf basaltic magmas cannot alone yield the andesites because their ∼61 to 64 wt.% SiO2 is attended by incompatible REE and HFSE abundances lower than in the basalts (e.g., Ce 77-105 in andesites vs 114-166 ppm in basalts; Zr 149-173 vs 183-237; Nb 21-25 vs 34-42). On the other hand, andesite mineral assemblages, textures, and compositions are consistent with basaltic magmas having mixed with rhyolitic magmas, provided the rhyolite(s) had relatively low REE and HFSE abundances. Linear binary mixing calculations yield good first approximation results for producing andesitic compositions from Sugarloaf basalt compositions and a central Arizona low-REE, low-HFSE rhyolite. For example, mixing proportions 52:48 of Sugarloaf basalt and low incompatible-element rhyolite yields a hybrid composition that matches Sugarloaf andesite well − although we do not claim to have exact endmembers, but rather, viable proxies. Additionally, the observed mineral textures are all consistent with hot basalt magma mixing into rhyolite magma. Compositional differences among the phenocrysts of Na-plagioclase, clinopyroxene, and amphibole in the andesites suggest several mixing events, and amphibole thermobarometry calculates depths corresponding to 8-16 km and 850° to 980 °C. The amphibole P-T observed for a rather tight compositional range of andesite compositions is consistent with the gathering of several different basalt-rhyolite hybrids into a homogenizing 'collection' zone prior to eruptions. We interpret Sugarloaf Mountain to represent basalt-rhyolite mixings on a relatively small scale as part of the large scale Miocene (∼20 to 15 Ma) magmatism of central Arizona. A particular qualification for this example of hybridization, however, is that the rhyolite endmember have relatively low REE and HFSE abundances.
Related Topics
Physical Sciences and Engineering Earth and Planetary Sciences Geochemistry and Petrology
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