Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8862925 | Sustainable Environment Research | 2018 | 41 Pages |
Abstract
Chlorothalonil is a pesticide that can contaminate water bodies, detriment aquatic organisms, and cause cancers of the forestomach and kidney. In this study, a powdered activated carbon prepared from casuarina wood was used for the adsorption of chlorothalonil from aqueous solutions. Based on Scanning Electron microscopy and Fourier Transform Infrared Spectroscopy analyses, the adsorbent material comprised pores and multiple functional groups that favored the entrapment of chlorothalonil onto its surface. At initial chlorothalonil concentration of 480 mg Lâ1, the equilibrium uptake capacity was 187 mg gâ1 at pH: 7, adsorbent dosage: 0.5 g Lâ1, contact time: 40 min, and room temperature (25 ± 4 °C). The kinetic and isotherm studies indicated that the rate constant of pseudo-second-order model (k2) was 0.003 g mgâ1 minâ1, and the monolayer adsorption capacity was 192 mg gâ1. Results from a quadratic model demonstrated that the plot of adsorption capacity versus pH, chlorothalonil concentration, adsorbent dosage, and contact time caused quadratic-concave, linear-up, flat, and quadratic-linear concave up curves, respectively. An artificial neural network with a structure of 4-5-1 was able to predict the adsorption capacity (R2: 0.982), and the sensitivity analysis using connection weights showed that pH was the most influential factor. An economic estimation using amortization and operating costs revealed that an adsorption unit subjected to 100 m3 dâ1 containing chlorothalonil concentration of 250 ± 50 mg Lâ1 could cost 1.18 $ mâ3.
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Authors
Mohamed Gar Alalm, Mahmoud Nasr,