Paired carbonate-organic carbon and nitrogen isotope variations in Lower Mississippian strata of the southern Great Basin, western United States

The δ15N across the K-O δ13C excursion in the distal ramp section is decoupled from δ13C, with the majority of δ15N values around 4 ± 1‰ that do not show any obvious temporal trend. In contrast, δ15N values in the shallow-water section is coupled with the K-O δ13C excursion, with a 3‰ positive shift from 4‰ to 7‰ at the rising limb of the δ13C excursion and a negative shift from 7‰ to 1-2‰ at the falling limb of the δ13C excursion. The δ15N trend from the distal ramp section is, in some extent, comparable with that documented from a section in South China, while the coupled δ13C-δ15N pattern in the proximal section seems better explain the potential redox change across a prominent δ13C excursion. Considering the sensitivity of δ15N to redox conditions of depositional environments, a more comprehensive δ15N study in a broader paleogeographic context is required to better understand the interactions between carbon and nitrogen cycles across the K-O interval-a critical transition from the mid-Paleozoic greenhouse clime to Late Paleozoic Ice Age (LPIA).