Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8914636 | Quaternary Science Reviews | 2018 | 17 Pages |
Abstract
This study provides a detailed geochemical record of one of the best studied loess-paleosol sequences (LPS) in Hungary covering Marine Isotope Stage (MIS) 6 to MIS 2. SüttÅ is situated in the northwestern Carpathian Basin at the transition between oceanic and continental climate. We investigated weathering intensity, dust provenance and sedimentation dynamics by high-resolution X-ray fluorescence (XRF) scanning of discrete samples in comparison with quantitative XRF and other published proxy data such as grain-size, magnetic susceptibility and micromorphology. Multivariate statistics unravel pedogenesis in terms of decalcification and grain-size dynamics as processes controlling the elemental composition. Furthermore, high-resolution chemostratigraphy indicates geochemical homogeneity for mature MIS 5 paleosols and the modern soil. Together with the A-CN-K plot providing no hint for K-feldspar weathering, semi-arid continental paleoenvironmental conditions are considered as prevailing. Dust provenance is studied by geochemical reference literature data from potential ultimate dust source areas, Th/metal ratios and comparison with the composition of the upper continental crust (UCC). Results indicate a felsic rock composition and a stable dust source, albeit immediate (adjacent Danube floodplains) and ultimate dust sources (surrounding mountain belts) need to be distinguished. According to the Sr-K-Rb plot, the Austroalpine cover nappes area northwest of SüttÅ might be the dominant ultimate dust source. The weathering-resistant elements Al, Ti and Zr as well as Zr/metal ratios indicate Zr addition and thus strongest sediment sorting and/or recycling during MIS 6. Since Al, Ti and Zr show minimal correlations with grain-size, we suggest a cascade-alike transport pathway from ultimate source to sink involving multiple sediment recycling and sorting cycles in both fluvial and eolian domains. Therefore, this study highlights how high-resolution qualitative geochemical data contributes to a better understanding of paleoenvironmental and sedimentation dynamics at LPS. Application of such a versatile geochemical screening tool is of broad interest to the scientific community working on (terrestrial) paleoenvironmental archives that are commonly discretely sampled.
Keywords
Related Topics
Physical Sciences and Engineering
Earth and Planetary Sciences
Geology
Authors
Jörn Profe, Lena Neumann, Ágnes Novothny, Gabriella Barta, Christian Rolf, Manfred Frechen, Christian Ohlendorf, Bernd Zolitschka,