Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8917715 | Current Opinion in Electrochemistry | 2017 | 5 Pages |
Abstract
Electrosynthesis offers an interesting alternative to the classical synthesis of organoboronic derivatives. Aryl-, allyl- and benzylboronic acids can be prepared via the reduction of organic halides in the presence of trialkylborates or pinacolborane. Electrochemical methodology avoids the use of noble metals and of low temperatures. It also allows the use of more accessible organic chlorides as starting substrates. With dihalogenated derivatives, good borylation selectivities can be obtained. 63
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Sandra Olivero, Elisabet Duñach,