Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8948512 | Ceramics International | 2018 | 26 Pages |
Abstract
The bismuth layer-structured Na0.5Bi4.5-xPrxTi4O15 (xâ¯=â¯0, 0.1, 0.2, 0.3, 0.4, and 0.5) (NBT-xPr3+) ceramics were fabricated using the traditional solid reaction process. The effect of different Pr3+ contents on dielectric, ferroelectric and piezoelectric properties of Na0.5Bi4.5Ti4O15 ceramics were investigated. The grain size of Pr3+-doping ceramics was found to be smaller than that of pure one, the maximum dielectric constant and Curie temperature Tc gradually decreased with increasing Pr3+ contents, and the dielectric loss decreased at high temperature by Pr3+-doping. Moreover, the activation energy (Ea), resistivity (Z'), remanent polarization (2Pr) and piezoelectric constant (d33) increased by Pr3+-doping. The NBT-xPr3+ ceramics with xâ¯=â¯0.3 achieved the optimal properties with the maximum dielectric constant of 1109.18, minimum loss of 0.00822 (250â¯kHz), Ea of 1.122â¯eV, Z' of 7.9â¯kΩâ¯cm (725 ºC), d33 of 18 pC/N, 2Pr of 12.04 μC/cm2. The enhancement was due to the addition of Pr3+ which suppressed the decreasing of resistivity at high temperature and made it possible for NBT-xPr3+ ceramics to be poled in perpendicular direction, implying that it is a great improvement for Na0.5Bi4.5Ti4O15 ceramics in electrical properties.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Yong Chen, Can-Can Zhang, Lu Qin, Chao-Bin Jiang, Kang-Hui Liu, Chao Ma, Zhen-Tao Wu, Rui-Kun Pan, Wan-Qiang Cao, Cong Ye, Zhang Li,