Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
8953409 | Journal of Saudi Chemical Society | 2018 | 7 Pages |
Abstract
A highly stereoselective dibromination of diphenylphosphorylallenes using N-bromosuccinimide (NBS) as bromine reagent is developed, wherein a variety of 2-bromo-substituted allyl bromides were obtained in good to excellent yields under mild reaction conditions. Moreover, the dibromination reaction allows a gram-scale synthesis of 2-bromo-substituted allyl bromides, and the products could be successfully transformed to various valuable derivatives.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Qiang Wang, Li-Heng Ruan, Jing Sun, Ming-Dong Zhou,