Groundwater recharge, circulation and geochemical evolution in the source region of the Blue Nile River, Ethiopia

Geochemical and environmental isotope data were used to gain the first regional picture of groundwater recharge, circulation and its hydrochemical evolution in the upper Blue Nile River basin of Ethiopia. Q-mode statistical cluster analysis (HCA) was used to classify water into objective groups and to conduct inverse geochemical modeling among the groups. Two major structurally deformed regions with distinct groundwater circulation and evolution history were identified. These are the Lake Tana Graben (LTG) and the Yerer Tullu Wellel Volcanic Lineament Zone (YTVL). Silicate hydrolysis accompanied by CO2 influx from deeper sources plays a major role in groundwater chemical evolution of the high TDS Na-HCO3 type thermal groundwaters of these two regions. In the basaltic plateau outside these two zones, groundwater recharge takes place rapidly through fractured basalts, groundwater flow paths are short and they are characterized by low TDS and are Ca-Mg-HCO3 type waters. Despite the high altitude (mean altitude ∼2500 masl) and the relatively low mean annual air temperature (18 °C) of the region compared to Sahelian Africa, there is no commensurate depletion in δ18O compositions of groundwaters of the Ethiopian Plateau. Generally the highland areas north and east of the basin are characterized by relatively depleted δ18O groundwaters. Altitudinal depletion of δ18O is 0.1‰/100 m. The meteoric waters of the Blue Nile River basin have higher d-excess compared to the meteoric waters of the Ethiopian Rift and that of its White Nile sister basin which emerges from the equatorial lakes region. The geochemically evolved groundwaters of the YTVL and LTG are relatively isotopically depleted when compared to the present day meteoric waters reflecting recharge under colder climate and their high altitude.