Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9460481 | Journal of Aerosol Science | 2005 | 14 Pages |
Abstract
The mobility distributions of electrosprays from solutions of relatively large tetraalkyl ammonium halide salts A+B- produce a series of sharp peaks associated to clusters of the form (A+)z(AB)n, dominated by the bare cation A+. In order to facilitate their use as standards of mass and mobility (in air), these properties are characterized via tandem use of a differential mobility analyzer (DMA) and a mass spectrometer (MS) with an atmospheric pressure inlet. Mobility diameters (based on Millikan's conventional size vs. mobility relation) in excess of 3Â nm are obtained from singly and doubly charged clusters. The mobilities of the ions A+(AB)3 are anomalously large for alkyl groups from methyl to butyl, presumably due to their relatively high symmetry.
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Authors
S. Ude, J. Fernández de la Mora,