Accumulation of carbon, nitrogen and phosphorus during soil formation on alder spoil heaps after brown-coal mining, near Sokolov (Czech Republic)

Rapid accumulation of C and N in the soil profile was registered within 15 years after reclamation. The rate of increase in C and N contents in the whole profile and the thickness of the litter and fermentation layers was slower in 25-year-old and older reclaimed sites. The soil of the semi-natural alder forest was richer in C and N in the 5-10-cm layer compared with 40-year-old (clays) and even with 65-year-old (gravel-sand) reclaimed soils. N accumulated more slowly in comparison with C, especially in deeper (5-10 cm) parts of the profile. Accumulation of organic C resulted in a decrease in substrate pH from alkaline, which was characteristic of young sites, to slightly acidic on older sites. The pH decreased gradually with increasing site age in all soil layers but increased with depth in the soil profile. In contrast to C and N, P content did not significantly change with site age in any layer of the soil profile. The highest amount of P was found in the fermentation layer, but there was no difference to the other layers. The soil profile of the semi-natural sites was richer in P in comparison to 40-year-old reclaimed ones.