| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9557351 | Phytochemistry | 2005 | 8 Pages |
Abstract
A brassinosteroid biosynthetic pathway from teasterone/typhasterol via 2,3-epoxybrassinosteroids to castasterone has been found in seedlings of Secale cereale. Epoxide hydrolysis resulting in stereoisomeric vicinal 2,3-diols followed by inversion of configuration at C-2 and C-3 was demonstrated by stepwise administration of deuterated precursors and HPLC-ESI-MS-SIM detection.
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Authors
Andrey Antonchick, Aleš Svatoš, Bernd Schneider, Olga V. Konstantinova, Vladimir N. Zhabinskii, Vladimir A. Khripach,