| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9562351 | Progress in Polymer Science | 2005 | 33 Pages |
Abstract
This review describes polymer synthesis utilizing carbon dioxide and carbon disulfide as useful C1 resources. Chain and step copolymerizations are recounted with polymerizations of cyclic carbonates, especially five-membered ones, as monomers derived or potentially obtainable from carbon dioxide. Homopolymerization, copolymerizations, and application as a precursor for reversible chain transfer agents for RAFT polymerization are described for carbon disulfide based polymer synthesis. As polymerizations of monomers from carbon disulfide, ring-opening polymerizations of dithiocarbonates and thiourethanes are described.
Keywords
NMPCP MASTMUN,N-Dimethyl acetamideTfOHPentamethylcyclopentadienylBPOCopolymerizationDTBPLcstDMACDSCGMADTCFMOCMMADBUPHATHFnuclear magnetic resonanceCp*n-methyl pyrrolidoneε-CaprolactoneSalenTrifluoromethanesulfonic acidcyclohexene oxidePropylene oxideChobenzoyl peroxideTetrahydrofuranNMRDomaDOAglass transition temperatureLower critical solution temperaturecarbon disulfideDithiocarbonateCarbon dioxideRAFTFT-IRMethyl methacrylateweight-average molecular weightnumber-average molecular weightRing-opening polymerizationDifferential scanning calorimetryCarbonateethylene carbonatePropylene carbonateGlycidyl methacrylate
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Bungo Ochiai, Takeshi Endo,