| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9563317 | Tetrahedron | 2005 | 11 Pages |
Abstract
The mechanisms of: (a) keto-enol tautomerism, (b) pinacol rearrangement, and (c) methanediol decomposition were studied by means of AIM and Hirshfeld atomic partitionings. The three processes follow concerted mechanisms, but a hydrogen-bridged structure is never formed along the reaction path of the pinacol rearrangement.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Marcos Mandado, Ricardo A. Mosquera, Ana M. Graña, Christian Van Alsenoy,