Article ID Journal Published Year Pages File Type
9563585 Tetrahedron 2005 4 Pages PDF
Abstract
Aminolysis behavior of cyclic carbonates bearing directly bound alicyclic structure is investigated as a fundamental study for syntheses of hydroxyurethanes with alicyclic structure including poly(hydroxyurethane)s. Kinetic studies and computational calculation revealed that the conformational constraint from the alicyclic ring affects the reactivity of the carbonate ring.
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Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
Kinetic and computational studies on aminolysis of bicyclic carbonates bearing alicyclic structure giving alicyclic hydroxyurethanes
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