| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9567062 | Applied Surface Science | 2005 | 4 Pages |
Abstract
The amphiphilic chromo-ionophore 2-[(1E,3E)-4-(2,3,5,6,8,9,11,12,14,15-decahydro-1,7,10,16,4,13-benzotetraoxadithiacyclooctadecin-18-yl)-1,3-butadienyl]-3-octadecyl-1,3-benzothiazol-3-ium perchlorate (AB211) forms mixed monolayers at the air-water interface with the phospholipid l-α-dimyristoylphosphatidylcholine (DMPC) as deduced from surface pressure-area and surface potential-area isotherms. In contrast to the behaviour of pure monolayers of AB211 on water, no association of the chromophores is observed by reflection spectroscopy. Upon compression of the mixed monolayer AB211:DMPC = 1:5, a re-orientation of the chromophores from flat to tilted is observed, presumably assisted by the stretching of the choline group of the phospholipid molecules acting a matrix.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
T.I. Sergeeva, S.P. Gromov, A.I. Vedernikov, M.S. Kapichnikova, M.V. Alfimov, D. Möbius, S.Yu. Zaitsev,