Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9575125 | Chemical Physics | 2005 | 12 Pages |
Abstract
On the basis of two many-particle models of a geminate reaction A + B â Product in the presence of bulk scavengers C for which the closed kinetic equations for the mean concentration of species can be exactly derived the unified form of integro-differential equation of general kinetic theory is obtained. A clear physical interpretation has been done for every term of the equations. For low concentration [C] of scavengers, the kinetic equations are reduced to the so-called quasi-binary ones that in turn are brought into the equivalent regular form (the rate type equations).
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
A.A. Kipriyanov, S.G. Fedorenko, A.B. Doktorov,