Article ID Journal Published Year Pages File Type
9575125 Chemical Physics 2005 12 Pages PDF
Abstract
On the basis of two many-particle models of a geminate reaction A + B → Product in the presence of bulk scavengers C for which the closed kinetic equations for the mean concentration of species can be exactly derived the unified form of integro-differential equation of general kinetic theory is obtained. A clear physical interpretation has been done for every term of the equations. For low concentration [C] of scavengers, the kinetic equations are reduced to the so-called quasi-binary ones that in turn are brought into the equivalent regular form (the rate type equations).
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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