Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9575137 | Chemical Physics | 2005 | 17 Pages |
Abstract
We consider tunneling-mediated electron transfer through time dependent bridges. An approach is developed for computing corrections to the time dependent tunneling matrix element that arise from the breakdown of the Born-Oppenheimer Adiabatic approximation. Differences between Franck-Condon and Born-Oppenheimer breakdown are discussed in the context of bridge-mediated tunneling.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Antonios Teklos, Spiros S. Skourtis,