Article ID Journal Published Year Pages File Type
9575452 Chemical Physics 2005 6 Pages PDF
Abstract
We present a detailed investigation of the quantum efficiency of the 1S0 and 3P0,1 levels in Pr3+ doped YF3 under VUV excitation. The quantum efficiency of the 3P0,1 level was determined by the measurement and comparison of the photon fluxes of the 1S0 → 1I6 transition around 400 nm with the visible emissions occurring from the 3P0,1 levels. It was found that already at concentrations as low as 0.01% the 3P0,1 emission quantum efficiency is only about 61%. The quenching process is most probable caused by an energy transfer cross relaxation process involving the 3P0,1 levels and the 3H4 ground state. For concentrations of 0.1%, 0.5%, 1% and 10%, the quantum efficiency was determined to be about 42%, 29%, 17%, and 0.4%, respectively. The total quantum efficiency of the visible emission (380-750 nm) under excitation at 190 nm, determined by measurements of the total photon flux, has a maximum for a Pr3+ concentration of 1%. At this value, the absorption efficiency of the 4f5d absorption bands is very high and the 3P0,1 quenching is only moderate.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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