| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9577245 | Chemical Physics Letters | 2005 | 6 Pages |
Abstract
The method for analyzing the 2H NMR spectrum affected by strong paramagnetic interaction is discussed. The 2H NMR spectral simulation including the effects of paramagnetic shift and paramagnetic spin-spin relaxation was performed for several molecular motions. The contribution of distant paramagnetic ions to the paramagnetic shift and the effect of anisotropic spin-spin relaxation on the lineshape of the 2H NMR spectrum were investigated by the spectral simulation. The temperature variation of 2H NMR spectrum of [Mn(H2O)6][SiF6] observed by the Exorcycled quadrupole-echo sequence was well reproduced using the proposed method.
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Authors
Motohiro Mizuno, Naohisa Itakura, Kazunaka Endo,