Article ID Journal Published Year Pages File Type
9577335 Chemical Physics Letters 2005 5 Pages PDF
Abstract
We report a combined shear small-angle neutron scattering (shear-SANS) and rheo-optical study of dilute aqueous suspensions of SWNT bundles dispersed using ionic surfactants. Both shear-SANS and flow birefringence reveal weak shear-induced alignment of SWNT bundles along the direction of flow. In terms of a nematic order parameter, the degree of alignment is found to increase with the shear rate, reaching ca. 0.08 at 2000 s−1. Addition of a soluble polymer to the SWNT suspensions diminishes shear-induced alignment. The factors limiting shear alignment in dilute SWNT suspensions are discussed.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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