| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9577489 | Chemical Physics Letters | 2005 | 5 Pages |
Abstract
Electrochemical oxidation of (C6H5)3PN(C6H5) and (C6H5)3PN(C6H5) leads to EPR spectra which reveal the dimeric structure of the resulting radical cation. In contrast to this behaviour, oxidation of bis-iminophosphorane leads to [(C6H5)3PN(C6H4)N=P(C6H5)3]+: In these species the unpaired electron is delocalized on the N(C6H4)N moiety and the persistency of the radical depends upon the relative position of the two PN bonds.
Related Topics
Physical Sciences and Engineering
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Authors
Adil Matni, Leila Boubekeur, Nicolas Mezailles, Pascal Le Floch, Michel Geoffroy,