Article ID Journal Published Year Pages File Type
9577604 Chemical Physics Letters 2005 4 Pages PDF
Abstract
A new view of post-collision interaction is obtained in two-dimensional maps of the electron distributions from double photoionisation of Ge(IV) compounds, occurring by the Auger effect via hole creation in the 3d shell. The peak shifts of the photolines are well modelled by the formula of Kuchiev and Scheinerman [M.Yu. Kuchiev, S.A. Scheinerman, Sov. Phys. JETP, 63 (1986) 986] which allows the intrinsic hole state lifetimes to be determined independently of line broadening by apparatus effects or molecular interactions. Separate double photoionisation spectra from direct or Auger ionisation processes are obtained and compared.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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