Article ID Journal Published Year Pages File Type
9577674 Chemical Physics Letters 2005 5 Pages PDF
Abstract
On the basis of the definition of overlap polarizability of a chemical bond we propose that the overlap region in a molecule AB behaves as a localized plasma-like harmonic oscillator. Strong absorption and inelastic scattering by this oscillator are predicted in the far ultraviolet and near soft-X-ray spectral regions. Numerical estimates for representative diatomic molecules show a clear correlation with covalency, and suggest these absorption and inelastic scattering processes as a useful tool to characterize a chemical bond.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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