| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9577768 | Chemical Physics Letters | 2005 | 5 Pages |
Abstract
Matrix isolation infrared spectra and density functional calculations of the end-on and side-on bonded titanium monoxide-dinitrogen complexes were reported. These species were prepared by the reactions of laser-evaporated titanium monoxide with N2 or titanium atom with N2O in solid argon. The ground state TiO molecules or Ti atoms reacted with N2 or N2O to form the end-on bonded OTiNN complex spontaneously on annealing. This complex rearranged to the side-on bonded OTi(N2) molecule upon visible light irradiation.
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Authors
Mohua Chen, Guanjun Wang, Mingfei Zhou,