Article ID Journal Published Year Pages File Type
9577978 Chemical Physics Letters 2005 5 Pages PDF
Abstract
Excited state proton transfer (ESPT) of pyranine (8-hydroxypyrene-1,3,6-trisulfonate) is studied in a lysozyme-cetyltrimethylammonium bromide (CTAB) complex using picosecond emission spectroscopy. The critical association concentration (CAC) of CTAB is found to be ∼0.4 mM. Using a kinetic analysis it is shown that deprotonation, recombination and dissociation of the geminate ion pair in the lysozyme-CTAB aggregate are faster than that in a CTAB micelle.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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