Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9578030 | Chemical Physics Letters | 2005 | 5 Pages |
Abstract
Experimental studies of adsorption and desorption of molecular hydrogen on an amorphous porous solid water ice surface between 10 and 35Â K reveal a very efficient isotopic segregation process. A statistical model, which take into account thermodynamic aspects of adsorption sites and isotopic competition, is proposed to understand the enhancement of deuterium fractionation. This mechanism could play a key role in chemistry at the surface of interstellar dust grains.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
F. Dulieu, L. Amiaud, S. Baouche, A. Momeni, J.-H. Fillion, J.L. Lemaire,