Article ID Journal Published Year Pages File Type
9578030 Chemical Physics Letters 2005 5 Pages PDF
Abstract
Experimental studies of adsorption and desorption of molecular hydrogen on an amorphous porous solid water ice surface between 10 and 35 K reveal a very efficient isotopic segregation process. A statistical model, which take into account thermodynamic aspects of adsorption sites and isotopic competition, is proposed to understand the enhancement of deuterium fractionation. This mechanism could play a key role in chemistry at the surface of interstellar dust grains.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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