Article ID Journal Published Year Pages File Type
9578227 Chemical Physics Letters 2005 7 Pages PDF
Abstract
Metastable fractions for the dissociation of fullerene cations Cn+→Cn-2++C2(42⩽n⩽70) have been measured in a three-sector-field mass spectrometer. They have been determined with the same experimental setup as the kinetic energy release data published recently. A statistical model which includes cooling by radiation as required by the timescale of the experiment is used to deduce dissociation energies from the metastable fractions. The results are compared with values extracted from our kinetic energy release data and other experiments.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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