| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9578261 | Chemical Physics Letters | 2005 | 5 Pages |
Abstract
An almost exact calculation of the statistical mechanics of a lattice model of benzene adsorption in the quasi one-dimensional pores of zeolites is presented. Our calculation attributes the experimentally observed steps in the level of adsorption with rising pressure, to re-orientational and positional transitions amongst molecules in the adsorbed phase. The model also satisfactorily reproduces the essential features of the very unusual temperature dependence of the isotherms.
Related Topics
Physical Sciences and Engineering
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Physical and Theoretical Chemistry
Authors
George Manos, Lawrence J. Dunne, Seyed E. Jalili,