| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9582392 | Chemical Physics Letters | 2005 | 5 Pages |
Abstract
Combination of pulsed field gradient (PFG) NMR with magic-angle spinning (MAS) NMR is demonstrated to have remarkable advantages in comparison with conventional PFG NMR, if applied to diffusion measurements in beds of nanoporous particles, notably zeolites. These advantages are based on the effect of line narrowing and concern: (i) a prolongation of the intervals during which the magnetic field gradients may be applied and a corresponding enhancement in the sensitivity towards small molecular displacements, and (ii) an enhanced resolution in the chemical shift scale. Both options are illustrated by measuring the diffusion coefficient of n-butane adsorbed in silicalite-1.
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Authors
André Pampel, Moisés Fernandez, Dieter Freude, Jörg Kärger,