Article ID Journal Published Year Pages File Type
9582420 Chemical Physics Letters 2005 7 Pages PDF
Abstract
The measured transitions are split into two component lines due to the tunnelling between two equivalent positions, with Kr above or below the FCF plane. The vibrational splitting, 79.19 (4) MHz, has been used to estimate the inversion barrier (1.23 (5) kJ mol−1), while an estimate of the dissociation energy (1.9 kJ mol−1) has been deduced from centrifugal distortion effects.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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