Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9585172 | Journal of Electron Spectroscopy and Related Phenomena | 2005 | 6 Pages |
Abstract
TiO2 films fabricated by DC reactive magnetron sputtering on quartz glass substrates were annealed in several different ways. The structure and properties of the films were characterized by UV-vis-NIR, PL spectra and X-ray photoelectron spectroscopy. For the annealed samples, it is interesting that a clear absorption peak was found at 496Â nm. The analysis of XPS spectra shows that oxygen can diffuse outward from the lattice, resulting in production of Ti3+ and oxygen vacancies. The PL spectra show that the absorption peak at 496Â nm is not induced by a transition within the forbidden band gap. Combining the XPS results with the linear combination of atomic orbital molecular orbital (LCAO-MO) theory and crystal-field (CF) theory, we can explain the appearance of this absorption peak. We conclude that the spectroscopic features result from the t2g*âeg* electronic transition in these TiO2 films.
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Physical and Theoretical Chemistry
Authors
Baoshun Liu, Xiujian Zhao, Qingnan Zhao, Xin He, Jingyang Feng,