Article ID Journal Published Year Pages File Type
9585377 Journal of Electron Spectroscopy and Related Phenomena 2005 4 Pages PDF
Abstract
Photoionization and fragmentation of CHF2Cl were studied with photoionization mass spectroscopy (PIMS) and photoionization efficiency spectroscopy (PIES) at NSRL. Ionization potential of CHF2Cl was obtained and major fragment ions CHF2+, CHFCl+, CHF+, and CF+ were observed with their appearance energies, respectively. Dissociation energies of some possible dissociation channels were deduced. The processes of photoionization and fragmentation of CHF2Cl are discussed based on the comparison between determined appearance energies and energies predicted by the Gaussian-2 calculations.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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