Article ID Journal Published Year Pages File Type
9585443 Journal of Electron Spectroscopy and Related Phenomena 2005 5 Pages PDF
Abstract
Double photoionisation spectra of HI, CH3I and CF3I have been measured by the TOF-PEPECO technique, providing complete information on electron energy distributions. The lowest energy states of HI2+ and CH3I2+ are identified and their vibrations are resolved. Possible reasons for the markedly different CF3I spectrum are discussed. There is evidence for atomic autoionisation of iodine as a pathway contributing to the double photoionisation.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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