Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9586147 | Journal of Luminescence | 2005 | 5 Pages |
Abstract
The compounds [3,3-(CO)2-3-NO-closo-3,1,2-ReC2B9H11] and [NEt4][3,3,3-(CO)3-8-I-closo-3,1,2-ReC2B9H10] have been shown to be emissive in MeTHF at 77 K, with λmax in the blue region of the visible spectrum. Emission from [3,3,3-(CO)3-8-I-closo-3,1,2-ReC2B9H10]-, which has been structurally characterized, is phosphorescent with a single exponential decay lifetime, Ï=1.65 ms. The complex [3,3-(CO)2-3-NO-closo-3,1,2-ReC2B9H11] also emits in the solid state at 298 K and has been shown by diffuse-reflectance UV-vis measurement to have a band gap of 2.66 eV.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Matthew J. Fischer, Paul A. Jelliss, Justin H. Orlando, Lisa M. Phifer, Nigam P. Rath,