Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9588580 | Journal of Molecular Liquids | 2005 | 4 Pages |
Abstract
The diffusion phenomena were analyzed using the phenomenological equations of the thermodynamics of irreversible processes. The diffusion coefficient was thought to be dependent on local concentrations and pressure, unlike it was done in the linear theories. The reversible chemical reactions were modeled as intermolecular interaction. The ideal and regular solutions and solutions, described by the Margules's and Sketchard-Hammer's equations, were investigated and analytical solutions were found.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
K.V. Cherevko, D.A. Gavryushenko, J.V. Kulyk, V.M. Sysoev,