Article ID Journal Published Year Pages File Type
9588580 Journal of Molecular Liquids 2005 4 Pages PDF
Abstract
The diffusion phenomena were analyzed using the phenomenological equations of the thermodynamics of irreversible processes. The diffusion coefficient was thought to be dependent on local concentrations and pressure, unlike it was done in the linear theories. The reversible chemical reactions were modeled as intermolecular interaction. The ideal and regular solutions and solutions, described by the Margules's and Sketchard-Hammer's equations, were investigated and analytical solutions were found.
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Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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