Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9588819 | Journal of Molecular Liquids | 2005 | 6 Pages |
Abstract
Rate constants have been measured spectrophotometrically for the reactions of p-nitrophenyl acetate (PNPA) with some α-effect nucleophiles, i.e., acetohydroxamate, benzohydroxamate, and salicylhydroxamate ions in dimethylsulfoxide, dimethylformamide, 1,4-dioxane, and acetonitrile-water mixtures of varying compositions (10-80% v/v) at 27 °C (pH 7.7). All the three hydroxamates exert a large α-effect in H2O. The reactivity of hydroxamates towards PNPA depends upon the nature of substrate and solvents. The kinetic results have been explained on the basis of basicities (pKa), solvation effect, α-effect, and ground state destabilization.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Kallol K. Ghosh, Manmohan Lal Satnami, Daliya Sinha, Jyoti Vaidya,