| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9589491 | Journal of Molecular Spectroscopy | 2005 | 18 Pages |
Abstract
In this paper, we use the algebraic approach to describe the vibrational modes of stibine molecule (of C3v molecular symmetry group) up to 21 quanta. As the stibine molecule exhibits stretch-bend resonances, we build an algebraic pyramidal coupling operator between stretching modes and bending modes adapted to this molecule. The standard deviation associated to the fit of the vibrational levels is 1.75Â cmâ1.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
L. Pluchart, C. Leroy, N. Sanzharov, F. Michelot, E. Bekhtereva, O. Ulenikov,